Citation:
YAN Xiu-Ru, SONG Kuan-Xiu, HUO Ming-Liang, FU Xian-Song, XIN Chun-Wei. Preparation and Photocatalytic Degradation Activity of Nanometer SnO2[J]. Chinese Journal of Applied Chemistry,
;2002, 19(8): 750-753.
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Nanometer SnO2 particles have been prepared from SnCl4·5H2O by precipitation and followed by calcination. The structure and morphology of the product were characterized by IR, XRD, SEM, TEM and BET techniques. The results indicated the products were rutile SnO2 with average particle size of 8 nm, specific surface of 54.186 m2/g. At the preparation conditions:c(SnCl4)=5.7×10-2mol/L, pH=5.0, hydrolysis temperature 3℃, and calcination temperature 680℃, the sample with best photocatalytic degradation activity was obtained. The degradation degree of dimethyldichlorovinyl phosphate(DDVP) reached 18.32% after 30 min illumination in the presence of nanometer SnO2.
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