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Citation: WANG Hong-Qing, YANG Feng-Ling, LIU Zhao-Jie. Synthesis and Biological Activity of Alkoxyl-4-methylthiophenoxy Phosphoramidates[J]. Chinese Journal of Applied Chemistry, ;2002, 19(8): 746-749. shu

Synthesis and Biological Activity of Alkoxyl-4-methylthiophenoxy Phosphoramidates

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Institute of Organic Synthesis, Central China Normal University, Wuhan 430079
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Corresponding author: LIU Zhao-Jie,
Received Date: 26 December 2001
Available Online: 19 March 2002
Fund Project: 国家计划委员会攻关项目(97-563-02-05)资助课题 (97-563-02-05)

Fourteen alkoxyl-4-methylthiophenoxy phosphoramidates were synthesized by one-pot reaction process in toluene with yields of 45.9%~95.9%. Their structures were characterized by elemental analysis, IR and NMR spectroscopy. Their insecticidal activities were tested. They showed remarkable activities, mortality for aphid in nearly 100% at concentration of 0.012 5%(mass fraction). The cropland trial of compound 4e showed not only better mortality but also smaller dose than the methamidophos on aphid and spider mite.
- organophosphorous compound,
- phosphoramidate,
- synthesis,
- insecticidal activity
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