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Citation: PENG Yi-Ru, CHEN Nai-Sheng, HUANG Jin-Ling, LIN Zhi-Peng, XUE Jin-Ping. Synthesis and Characterization of Tetra Potassium Salt of Zinc Tetra Sulfophthalocyanine[J]. Chinese Journal of Applied Chemistry, ;2002, 19(8): 730-733. shu

Synthesis and Characterization of Tetra Potassium Salt of Zinc Tetra Sulfophthalocyanine

PENG Yi-Ru ^a,b,c ,
CHEN Nai-Sheng ^a,c,, ,
HUANG Jin-Ling ^a,c ,
LIN Zhi-Peng ^a,c ,
XUE Jin-Ping ^a,c

1.
a Institute of Funcational Materials, Fuzhou University, Fuzhou 350002;
2.
b Department of Chemistry, Fujian Normal Unversity, Fuzhou
3.

Corresponding author: CHEN Nai-Sheng,
Received Date: 17 December 2001
Available Online: 15 April 2002
Fund Project: 国家自然科学基金(29871008) (29871008)福建省自然科学基金(C0110006) (C0110006)福建省教委(JA01020)资助项目 (JA01020)

The monopatassium salt of 4-sulfophthalic acid and monopotassium salt of 4-sulfophthalonitrile were synthesized and condensed to give tetrapotassium salt of zinc tetra sulfophthalocyanine by the solid fusion method or reaction in an inert solvent in the presence of (NH₄)₂MoO₄, urea, ZnCl₂ and NH₄Cl. The results showed that the first method gave a better yield (46%). The structures of precursors and the end product were characterized by elemental analysis, IR, ¹H NMR and ¹³C NMR.
- zinc tetra sulfophthalocyanine tetrapotassium salt,
- sulfophthalic monopotassium salt,
- sulfophthalonitrile monopotassium salt,
- synthesis
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