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Citation: CHI Xing-Bao. Synthesis and Electrochemical Behaviour of Bridged Bis-tetrathiafulvalenes[J]. Chinese Journal of Applied Chemistry, ;2002, 19(9): 847-851. shu

Synthesis and Electrochemical Behaviour of Bridged Bis-tetrathiafulvalenes

CHI Xing-Bao ^,

1.
Department of Chemistry, Huaibei Coal Teachers College, Huaibei 235000

Corresponding author: CHI Xing-Bao,
Received Date: 8 January 2002
Available Online: 22 April 2002

A novel method for synthesis of briged bis-tetrathiafulvalenes has ben proposed. 2,3-Bis(2-cyanoethylthio)-6,7-(1,3-propylidenedithio)tetrathiafulvalene(5) was reacted with sodium methoxide to give monothiolate of tetrathiafulvalene(6), which on reacting with p-chloroxylene afforded a monobridged bis-tetrathiafulvalene(7). Deprotection and alkylation of (7) yielded two-bridged bis-tetrathiafulvalene(8). In cyclic voltammograms of both compound(7) and (8) there were two oxidation-reduction peaks. Their UV-Vis spectral absorbances were also found intensified.
- bridged bis-tetrathiafulvalene,
- synthsis,
- cyclic voltammetry,
- UV-Vis spectrum
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