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Citation: LU Kui, YUAN Nai-Xiang, ZHOU Zhi-Xian, WU Yang-Jie. Synthesis and Property of Tetraethoxy-carbonylmethoxy calix [4]arene[J]. Chinese Journal of Applied Chemistry, ;2002, 19(10): 958-962. shu

Synthesis and Property of Tetraethoxy-carbonylmethoxy calix [4]arene

1.
a Department of Chemistry and Chemical Engineering, Zhengzhou Institute of Technology, Zhengzhou;
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b Department of Chemistry, Zhoukou Teachers College, Zhoukou;
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c Department of Chemistry, Zhengzhou University, Zhengzhou 450052

Corresponding author: WU Yang-Jie,
Received Date: 25 December 2001
Available Online: 23 April 2002
Fund Project: 国家自然科学基金资助项目(29872034) (29872034)

25, 26, 27, 28-Tetraethoxycarbonylmethoxy calix [4]arene(3) was synthesized by reacting calix [4]arene(2) with ethyl bromoacetate using K₂CO₃ as base in acetone. The structure of (3) was characterized by elmenetal analysis, IR, UV, MS, ¹H and ¹³C NMR spectra. Compound 3 exist in "partial cone" conformations. The coordination behavior of the compound with four rare earth metal(Ⅲ) nitrates in acetonitrile were studied by fluorescence spectrometry. The stability constants(lg K_s) of the complexes of 3 with rare earth metal(Ⅲ) nitrates and Gibbs free energy change(-ΔG⁰) of the coordination reactions were calculated according to the modified Hilderbrand-Benesi equation. The calix [4]arene obtained exhibited a strong coordination ability with rare earth nitrates and good transportability for alkali metal ions throungh liquid membrane in order of Na⁺> K⁺> Li⁺.
- tetraethoxycarbonylmethoxy calix [4]arene,
- synthesis,
- coordination,
- ion transportation
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