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Citation: YANG Fa-Fu, YU Tian-Xiang, YANG Xian-Jin, LIN Shen. Selective Nitration of Calix [4] arene Tetraethers[J]. Chinese Journal of Applied Chemistry, ;2002, 19(11): 1112-1114. shu

Selective Nitration of Calix [4] arene Tetraethers

1.
a Department of Chemistry, Fujian Normal University, Fuzhou 350007;
2.
b Department of Chemistry, Wuhan University, Wuhan

Corresponding author: YANG Fa-Fu,
Received Date: 18 March 2002
Available Online: 17 May 2002
Fund Project: 福建省青年科技人才创新资金(2001J025) (2001J025)

mono-Nitro-, 1,3-bis-nitro-, tetra-nitro- and 1,2-bis-nitro-calix [4]arenes were obtained separately by treating calix [4]arene tetraethers with 65% HNO₃ and HOAc in the yields of 70%, 62%, 15% and 50%, respectively. The reaction mechanism has been discussed.
- calix [4]arene tetraether,
- selective nitration,
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