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Citation: CHEN Qiu-Yun, WANG Yi-Ning, LUO Qin-Hui. Synthesis and Luminescence Property of d-f Heterodinuclear Cryptates Eu(Ⅲ)-M(Ⅱ)(M=Zn²⁺,Ni²⁺)[J]. Chinese Journal of Applied Chemistry, ;2002, 19(12): 1197-1199. shu

Synthesis and Luminescence Property of d-f Heterodinuclear Cryptates Eu(Ⅲ)-M(Ⅱ)(M=Zn²⁺,Ni²⁺)

1.
a Department of Chemistry, Huangshan College, Huangshan, 245021;
2.
b Department of Chemistry, Nanjing University, Nanjing

Corresponding author: CHEN Qiu-Yun,
Received Date: 23 May 2002
Available Online: 5 August 2002
Fund Project: 安徽省教委自然科学基金重点资助项目(2002KJ296ZD) (2002KJ296ZD)

Two d-f heterodinuclear cryptates Eu(Ⅲ)-M(Ⅱ)(M=Zn²⁺, Ni²⁺) were synthesized and characterized by elemental analysis, IR and ES-MS. The fluorescence properties of the cyptates in acetonitrile solution show that inclusion of Zn²⁺ in the mononuclear europium(Ⅲ) cryptate increases the energy transfer between cryptand and europium(Ⅲ) ion, while the inclusion of Ni²⁺ in the cavity quenches the fluorescence of Eu(Ⅲ) cryptate.
- lanthanide(Ⅲ),
- d-f heterodinuclear cryptate,
- europium(Ⅲ),
- fluorescence
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Synthesis and Luminescence Property of d-f Heterodinuclear Cryptates Eu(Ⅲ)-M(Ⅱ)(M=Zn2+,Ni2+)

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通讯作者: 陈斌, bchen63@163.com

Synthesis and Luminescence Property of d-f Heterodinuclear Cryptates Eu(Ⅲ)-M(Ⅱ)(M=Zn²⁺,Ni²⁺)