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Citation: YANG Jin-Fei. Catalytical Synthesis of Tri(β-chloroethyl)phosphate over TiSiW₁₂O₄₀/TiO₂ Catalyst[J]. Chinese Journal of Applied Chemistry, ;2003, 20(2): 201-202. shu

Catalytical Synthesis of Tri(β-chloroethyl)phosphate over TiSiW₁₂O₄₀/TiO₂ Catalyst

YANG Jin-Fei ^,

1.
College of Chemistry and Environmental Science, Nanjing Normal University, Nanjing 210097

Corresponding author: YANG Jin-Fei,
Received Date: 9 June 2002
Available Online: 21 November 2002

The synthesis of tri(β-chloroethyl)phosphate(TCEP) from ethylene oxide and phosphorus oxychloride catalyzed by a solid super acid TiSiW₁₂O₄₀/TiO₂ has been studied. The optimun reactions conditions are:molar ratio of ethylene oxide to phosphorous oxychloride=3.10:1.00, catalyst amount 1.5%, 5 h and 30~45℃.
- tri(chloroethyl)phosphate,
- TiSiW₁₂O₄₀/TiO₂,
- synthesis
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Catalytical Synthesis of Tri(β-chloroethyl)phosphate over TiSiW12O40/TiO2 Catalyst

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通讯作者: 陈斌, bchen63@163.com

Catalytical Synthesis of Tri(β-chloroethyl)phosphate over TiSiW₁₂O₄₀/TiO₂ Catalyst