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Citation: QIAO Yan-Hong, YU Ming, SUN Ming, MIAO Fang-Ming. Synthesis and Characterization of Tetranuclear Copper Complex of O-Vanillin-Methionine[J]. Chinese Journal of Applied Chemistry, ;2003, 20(2): 192-194. shu

Synthesis and Characterization of Tetranuclear Copper Complex of O-Vanillin-Methionine

1.
a College of Chemistry and Life Science, Tianjin Normal University, Tianjin 300074;
2.
b Tianjin University of Science and Technology, Tianjin

Corresponding author: SUN Ming,
Received Date: 16 July 2002
Available Online: 4 November 2002
Fund Project: 教育部资助优秀青年教师基金(2000(11)号文件) (2000(11)号文件)天津市教委基金(990712) (990712)天津师范大学青年基金(52LE32)资助项目 (52LE32)

An O-Vanillin-methionine Schiff Base complex with copper(Ⅱ) has been synthesized under a mild condition. The complex has been characterized by elemental analysis, UV, FT-IR, TG-DTA and XRD. The crystal structure of the complex belongs to monoclinic, with space group C2/C, a=2.070 4(12) nm, b=1.431 9(8) nm, c=2.812 9(11) nm, β=133.15(2)°, V=6.084(5) nm³, Z=8, D_c=0.998 Mg/m³, F(000)=1 836, final R=0.121 8. The results revealed it is a tetranuclear copper(Ⅱ) complex.
- vanillin,
- methionine,
- Schiff Base,
- tetranuclear copper(Ⅱ) complex,
- synthesis
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