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Citation: WU Wen-Shi, LIU Shi-Xiong, HUAUG Zun-Xing. Syntheses and Crystal Structures of Zinc, Vanadium and Nickel Complexes Containing N-acetylpicoloylhydrazide[J]. Chinese Journal of Applied Chemistry, ;2003, 20(2): 138-143. shu

Syntheses and Crystal Structures of Zinc, Vanadium and Nickel Complexes Containing N-acetylpicoloylhydrazide

1.
a Central Laboratory, Fuzhou University, Fuzhou 350002;
2.
b College of Materials, Huaqiao University, Quanzhou

Corresponding author: LIU Shi-Xiong,
Received Date: 9 July 2002
Available Online: 29 November 2002
Fund Project: 福建省自然科学基金资助(E0210026,E0110010) (E0210026,E0110010)

Two title complexes [ZnL₂]·H₂O(1, C₁₆H₂₀N₆O₅Zn) and VO₂L(2, C₈H₈N₃O₄V; HL=N-acetylpicoloylhydrazide) have been synthesized. Their crystal data were determined for complex 1 space group C c, a=3.083 2(1) nm, b=0.759 31(3) nm, c=1.837 07(8) nm, β=116.918(2)°, V=3.834 8(3) nm³, Z=8, F(000)=1 824, μ=1.32 mm^-1, R=0.034 0, for 3 177 observed reflections(I≥2σ(I)); for complex 2 space group C2/c, a=1.012 2(3) nm, b=1.244 5(4) nm, c=1.694 1(5) nm, β=105.587(7)°, V=2.056(1) nm³, Z=8, F(000)=1 056, μ=0.967 mm^-1, R=0.057 7 for 1 268 observed reflections(I≥2σ(I)). The Zinc(Ⅱ) ion in complex 1 is coordinated with two pyridine nitrogen atoms, two diazine nitrogen atoms and two carbonyl oxygen atoms from two tridentate ligands, forming a distorted octahedral of N₄O₂. The vanadium atom in complex 2 is bound to two terminal oxygen atoms and one tridentate donor ligand in a distorted square pyramidal arrangement. There is an one-dimensional chain structure through the intermolecular hydrogen bonds and intramolecular hydrogen bonds in complex 1. Every two molecules in the crystal of complex 2 are linked by pairs through the intermolecular hydrogen bonds. The second harmonic generation I_2ω of complex 1 is 0.85 time as that of KDP.
- N-acetylpicoloylhydrazide,
- zinc complex,
- vanadium complex,
- nickel complex,
- crystal structure
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