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Citation: LIU Shu-Fen, ZHENG Ke, QU Ron-Jun, CHENG Guo-Xiang. Synthesis and Adsoption Property for Metal Ion of Polymeric Pseudo-Crown Ether[J]. Chinese Journal of Applied Chemistry, ;2003, 20(2): 125-129. shu

Synthesis and Adsoption Property for Metal Ion of Polymeric Pseudo-Crown Ether

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a Department of Chemistry, Yantai Normal College, Yantai 264025;
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b Yantai Institute of Goal Gas;
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c School of Material Science and Engineering, Tianjin University, Tianjin

Corresponding author: LIU Shu-Fen,
Received Date: 19 June 2002
Available Online: 12 September 2002
Fund Project: 国家自然科学基金(29906008)资助项目 (29906008)

Two novel polymeric pseudo-crown ethers were synthesized by three simple reactions. Their adsorption properties for metal ions were studied. The results showed that at 25℃ the polymers exhibited adsorption capacities for Ag⁺,Hg²⁺ and Pb²⁺ respectively of 1.006,0.919 and 0.658 mmol/g, when the ion concentration was 0.043 0,0.040 1 and 0.041 6 mol/L, respectively. There occurred an obvious oxidation-reduction course of adsorption of Ag⁺. The structures of the polymers and its complex with Ag⁺ were studied by FTIR spectra. The adsorption appeared to be a result of chelated chain formation between oxygen of crown ether and benzylalcohol with metal ions.
- polymeric pseudo-crown ether,
- synthesis,
- metal ions,
- adsorption property
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Synthesis and Adsoption Property for Metal Ion of Polymeric Pseudo-Crown Ether

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com