Citation:
CHEN Yi-Qing, SUN Duo-Xian, LIU Jun. Preparation and Properties of Sodium Alginate/IPDI Gel Microspheres[J]. Chinese Journal of Applied Chemistry,
;2003, 20(2): 112-116.
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Sodium alginate/IPDI(A-Na/IPDI) microspheres are prepared by exchanging calcium alginate (A-Ca)/IPDI gel microspheres, prepared by crosslinking of calcium alginate with isophorone diisocyanate(IPDI), with sodium citrate. When used for adsorbtion of Pb2+, the highest adsorption percentage of A-Na/IPDI gel microspheres is 99.57%. The limiting adsorption concentration is 0.434 μmol/L and the mass exchange capacity is 383 mg/g. Ion exchange velocity of A-Na/IPDI gel microspheres is much greater than that of chelating resin D418 and polyacrylate resin D113. A-Na/IPDI gel microspheres have rapid adsorption velocity and high selectivity for Pb2+, showing a promising application in adsorption of heavy metal ions in human blood.
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Keywords:
- sodium alginate,
- ion adsorbent,
- microsphere,
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