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Citation: YUAN Shu-Jun, CAI Chun, LU Chun-Xu. Synthesis of An Amphipathic Schiff Base Complex with Cu(Ⅱ)and Catalytic Oxidation of Benzyl Alcohol[J]. Chinese Journal of Applied Chemistry, ;2003, 20(3): 278-280. shu

Synthesis of An Amphipathic Schiff Base Complex with Cu(Ⅱ)and Catalytic Oxidation of Benzyl Alcohol

YUAN Shu-Jun ^a,b,, ,
CAI Chun ^a ,
LU Chun-Xu ^a

1.
a College of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094;
2.
b Department of Chemical Engineering, Yancheng Institute of Technology, Yancheng 224003

Corresponding author: YUAN Shu-Jun,
Received Date: 6 August 2002
Available Online: 8 November 2002

An amphipathic Schiff base complex with Cu(Ⅱ) was synthesized from p-cresol and dodecanoyl chloride with total yield of 36.8%. The structure and amphipathic property of the ligand and Cu complex have been investigated. The oxidation of benzyl alcohol catalyzed by the complex in alkali solution gave benzaldehyde in yield of 57.8%.
- Schiff base,
- Cu(Ⅱ)complex,
- benzyl alcohol,
- catalytic oxidation
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