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Citation: HE Shui-Yang, HU Ting, YANG Rui, ZHAO Jian-She, XUE Gang-Lin, SHI Qi-Zhen. Synthesis and Antibacterial Activity of Salicylaldehyde-1H-benzotriazol-1-acetyl hydrazone Complexes with Lanthanide Perchlorate[J]. Chinese Journal of Applied Chemistry, ;2003, 20(3): 205-209. shu

Synthesis and Antibacterial Activity of Salicylaldehyde-1H-benzotriazol-1-acetyl hydrazone Complexes with Lanthanide Perchlorate

1.
Department of Chemistry, Northwest University and Shaanxi Provincial Key Laboratory of Physico Inorganic Chemistry, Xi'an 710069

Corresponding author: HE Shui-Yang,
Received Date: 19 June 2002
Available Online: 29 November 2002
Fund Project: 陕西省自然科学基金(02H010) (02H010)

Salicylaldehyde-1H-benzotriazol-1-acetyl hydrazone (C₁₅H₁₃N₅O₂, H₂L, SBTH) and its seven complexes with lanthanide perchlorates RE(HL)₂ClO₄(RE=Pr, Nd, Sm, Eu,Gd, Tb and Dy) have been synthesized and confirmed by elemental analysis, chemical analysis and molar conductivity measurement. The IR, UV and ¹H NMR results indicate that the SBTH is bonded with RE³⁺ via the carbonyl and phenol oxygen and imidogen nitrogen, forming a pentacyclic and hexacyclic tridentate complex.The complexes show a certain antibacterial activity against leaf mold, bacilli and actinomyceto.
- rare earth,
- salicylaldehyde-benzotriazol acetyl hydrazone,
- complex,
- synthesis,
- bioactivity
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