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Citation: WAN Xin-Jun, SONG Ming-You, WU Rong, CHU Dao-Bao. Synthesis of Glyceraldehydes by Indirect Electro-oxidation[J]. Chinese Journal of Applied Chemistry, ;2003, 20(6): 578-581. shu

Synthesis of Glyceraldehydes by Indirect Electro-oxidation

1.
a Department of Chemistry, Chaohu College, Chaohu 238000;
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b College of Chemistry and Materials Science, Anhui Normal University, Wuhu

Corresponding author: WAN Xin-Jun,
Received Date: 5 December 2002
Available Online: 2 April 2003
Fund Project: 安徽省教育厅自然科学基金(2001kj179)资助项目 (2001kj179)

The precursor Ti(OEt)₄ was prepared by anodic dissolution of Ti in absolute ethanol and directly hydrolyzed to give nanocrystalline TiO₂ film on titanium electrode (Ti/nano-TiO₂) by a sol-gel process.The nanocrystalline TiO₂-Pt modified titanium (Ti/nano-TiO₂-Pt) electrode was prepared by electrodeposition of Pt on nanocrystalline TiO₂ film.Electrocatalytic activity of the Ti/nano-TiO₂-Pt electrode for oxidation of Mn²⁺ to Mn³⁺ and synthesis of glyceraldehydes were investigated by cyclic voltammetry and indirect electro-oxidation methods.Mn³⁺ could be regenerated by electrolysis at Ti/nano-TiO₂-Pt anode in heterogeneous MnSO₄/H₂SO₄ medium with current efficiency over 90%.Glyceraldehyde was prepared in yield of 91% by the proposed method.
- glyceraldehyde,
- indirect electro-oxidation synthesis,
- Ti/nano-TiO₂-Pt electrode
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