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Citation: LI Hua-Ming, JI Ming-Hui, LIN Hai-Qiang, SHU Huo-Ming, XING Fu-Biao, CHEN Man-Li. Catalytic Oxidation of Cyclohexene to Adipic Acid over Heteropolyacids[J]. Chinese Journal of Applied Chemistry, ;2003, 20(6): 570-573. shu

Catalytic Oxidation of Cyclohexene to Adipic Acid over Heteropolyacids

1.
a Department of Chemistry, Hainan Normal University, Haikou 571158;
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b State Key Laboratory for Physical Chemistry of Solid Surface, Department of Chemistry, Xiamen University, Xiamen

Corresponding author: LI Hua-Ming,
Received Date: 27 January 2003
Available Online: 22 April 2003
Fund Project: 海南省自然科学基金(29902) (29902)海南省教育厅科研基金(Hjkj200219)资助项目 (Hjkj200219)

The oxidation of cyclohexene to adipic acid catalyzed by heteropolyacids has been investigated,using 30% aqueous hydrogen peroxide as an oxidant,and dicarboxy licacids or 8-hydroxyquinoline as cocatalyst.Adipic acid in yield up to 75.0% was obtained in 6 h,in the presence of 8-hydroxy quinoline.When oxalic acid was used as cocatalyst in condition of 92℃,6 h,n(cyclohexene):n(H₃PW₁₂O₄₀):n(H₂C₂O₄):n(H₂O₂)=100:1:1:538,the yield of adipic acid was 70.1%.When cetyltrimethyl ammonium bromide or cetylpyridinium bromide was used as phase transfer catalyst,the yield of adipic acid was 73.1% and 71.6% respectively.Catalytic oxidation of cyclohexene oxide or trans-1,2-cyclohexanediol to adipic acid over tungtophosphoric acid were also carried out in order to confirm the reported mechanism of the reaction.
- cyclohexene,
- catalytic oxidation,
- hydrogen peroxide,
- heteropoly acid,
- adipic acid
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