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Citation: SUN Jian-Ping, BAI Yong-Lin, WU Hong-Cai, WEI Wei. Synthesis of A Soluble Poly(2-Methoxy-5-Octyloxy)-1, 4-Phenylene Vinylene and Its Conductive and Third-Order Nonlinear Optical Properties[J]. Chinese Journal of Applied Chemistry, ;2003, 20(6): 537-541. shu

Synthesis of A Soluble Poly(2-Methoxy-5-Octyloxy)-1, 4-Phenylene Vinylene and Its Conductive and Third-Order Nonlinear Optical Properties

1.
Institute of Photoelectric Technology and Solar Energy, School of Electronics and Information Engineering, Xi'an Jiaotong University, Xi'an 710049

Corresponding author: SUN Jian-Ping,
Received Date: 4 December 2002
Available Online: 31 March 2003
Fund Project: 国家自然科学基金资助项目(10075038) (10075038)

A soluble poly (2-methoxy-5-octyloxy)-p-phenylene vinylene (PMOCOPV) was synthesized through double etherification,chloromethylation and dehydrochlorination reactions.The structure of the PMOCOPV has been characterized by IR,UV-Vis,¹H NMR and GPC.The conductivity of I₂,Br₂,FeCl₃ and H₂SO₄ doped PMOCOPV was 47.2,21.6,32.5 and 2.7 S/cm,respectively.The third-order nonlinear optical property of PMOCOPV was studied by degenerate four-wave mixing (DFWM).The resonant value of 6.8×10^-10 esu at 532 nm and the off-resonant value of 1.2×10^-11 esu at 1064 nm of third-order optical nonlinear susceptibilities were measured respectively.
- poly (p-phenylene vinylene),
- conductivity,
- nonlinear optics,
- third-order nonlinear susceptibility,
- degenerate four-wave mixing
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