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Citation: WANG Jing-Ping, DUAN Xian-Ying, WU Qiang, NIU Jing-Yang. Preparation and Crystal Structure of the Charge-transfer Complex[(CH₃)₂NH₂]₃[HSiMo₁₂O₄₀]·2DMF·4H₂O[J]. Chinese Journal of Applied Chemistry, ;2003, 20(7): 672-675. shu

Preparation and Crystal Structure of the Charge-transfer Complex[(CH₃)₂NH₂]₃[HSiMo₁₂O₄₀]·2DMF·4H₂O

1.
School of Chemistry and Chemical Engineering, He'nan University, Kaifeng 475001

Corresponding author: NIU Jing-Yang,
Received Date: 28 October 2002
Available Online: 21 April 2003
Fund Project: 河南省教育厅基金(20011500024)资助项目 (20011500024)

A charge-transfer complex, [(CH₃)₂NH₂]₃[HSiMo₁₂O₄₀]·2DMF·4H₂O, has been synthesized and characterized. The crystal structure of the complex obtained in mixed solvent of acetonitrile and water has been determined by single crystal X-ray diffractometry. It is triclinic lattice, space group Pī, with a=1.210 1(2) nm, b=1.498 6(3) nm, c=1.499 2(3) nm, α=83.59(3)°, β=86.88(3)°, γ=87.09(3)°, V=2.694 9(9) nm³, D_c=2.683 9 g/cm³, Z=2 and R=0.031 0.
- charge-transfer complex,
- synthesis,
- crystal structure
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Preparation and Crystal Structure of the Charge-transfer Complex[(CH3)2NH2]3[HSiMo12O40]·2DMF·4H2O

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Preparation and Crystal Structure of the Charge-transfer Complex[(CH₃)₂NH₂]₃[HSiMo₁₂O₄₀]·2DMF·4H₂O