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Citation: LI Wen-Xian, HAN Feng-Meib, ZHAO Yong-Lianga. Synthesies and Characterization of Phenylphenacylsulfoxide Complexes with Light Rare Earth Perchlorate and Photoluminescence of Eu³⁺ Complex[J]. Chinese Journal of Applied Chemistry, ;2003, 20(7): 664-667. shu

Synthesies and Characterization of Phenylphenacylsulfoxide Complexes with Light Rare Earth Perchlorate and Photoluminescence of Eu³⁺ Complex

1.
a College of Chemistry & Chemical Engineering, Inner Mongolia University, Huhhot 010021;
2.
b State Key Laboratory of Rare Earth Materials Chemistry and Applications, Beijing 100871

Corresponding author: LI Wen-Xian,
Received Date: 16 October 2002
Available Online: 17 March 2003
Fund Project: 内蒙古自然科学基金(20001301) (20001301)

Five solid complexes of phenyl-phenacyl sulfoxide(L) with light rare earth perchlorate have been synthesized and characterized. Elemental analysis and TG-DTA results suggested the complexes have a composition of RE(ClO₄)₃·L₅·2H₂O(RE=La,Pr,Nd,Sm,Eu). IR and ¹H NMR spectra results indicated that the ligand is bonded with RE(Ⅲ) ions through one oxygen atom of carbonyl group and one oxygen atom of sulfoxyl group. The molar conductivies and IR data indicated that only two anions ClO₄^- are in coordination. The ligand in Eu³⁺ complex showed a sensitization effect on the fluorescence of RE³⁺.
- phenyl-phenacyl sulfoxide,
- light rare earth perchlorate complex,
- synthesis,
- photoluminescence
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Synthesies and Characterization of Phenylphenacylsulfoxide Complexes with Light Rare Earth Perchlorate and Photoluminescence of Eu3+ Complex

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通讯作者: 陈斌, bchen63@163.com

Synthesies and Characterization of Phenylphenacylsulfoxide Complexes with Light Rare Earth Perchlorate and Photoluminescence of Eu³⁺ Complex