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Citation: FAN Rui-Lan, JIAO Wei, BIAN Zhan-Xi, LI Bao-Guo. Synthesis and Characterization of N-Aryl-Ferrocenylacryl Amides[J]. Chinese Journal of Applied Chemistry, ;2003, 20(10): 959-962. shu

Synthesis and Characterization of N-Aryl-Ferrocenylacryl Amides

1.
College of Chemisity and Chemical Engineering, Inner Mongolia University, Hohhot 010021

Corresponding author: FAN Rui-Lan,
Received Date: 22 January 2003
Available Online: 22 April 2003
Fund Project: 内蒙古自治区教育厅基金(300318) (300318)内蒙古大学青年科学基金(202042)资助项目 (202042)

The reaction of ferrocenylacrylate with SOCl₂ using pyridine as catalyst produced ferrocenylacryl chloride(yield 45%), which in reaction with(substituted) anilines gave thirteen N-aryl-ferrocenylacryl amides(FcCH=CHCONHAr). The method is time saving and easy in seperation and purification of the products. The product compounds have been characterized by elemental analysis, IR and ¹H NMR spectra. The results indicate that the kind and position of the substituents in aniline ring greatly affected the conjugation system and coplanarity of the products.
- ferrocenylacrylyl chloride,
- N-aryl-ferrocenylacryl amide,
- synthesis
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