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Citation: MENG Yi, XU Yan-Jie, CHEN Li-Gong. A New Synthesis Route for Sex Pheromone of Pine Sawfly Diprion jingyuanensis[J]. Chinese Journal of Applied Chemistry, ;2004, 21(1): 98-100. shu

A New Synthesis Route for Sex Pheromone of Pine Sawfly Diprion jingyuanensis

1.
School of Pharmaceuticals Science & Technology, Tianjin University, Tianjin 300072

Corresponding author: CHEN Li-Gong,
Received Date: 14 March 2003
Available Online: 10 August 2003

The total synthesis of 3,7-dimethyl-2-tridecanyl propionate, the active component of the sex pheromone of pine sawfly Diprion jingyuanensis is reported. The new synthesis process starts from 2-methyloctanal, then through hydroxyethylenation, transetherification, Claisen rearrangement, hydroxymethylation, hydrogenation to give 3,7-dimethyl-2-tridecanol. Esterification of 3,7-dimethyl-2-tridecanol affords 3,7-dimethyl-2-tridecanyl propionate.
- pine sawfly,
- sex pheromone,
- dimethyl tridecanol,
- dimethyl tridecanyl ptopionate,
- Claisen rearrangement
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