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Citation: WU Zhen-Yi, YANG Sen-Gen, LIN Yong-Sheng, CHENG Da-Dian, ZHAN Meng-Xiong. Synthesis and Redox Behavior of Complex CoC₆₀(OH)[J]. Chinese Journal of Applied Chemistry, ;2004, 21(1): 81-83. shu

Synthesis and Redox Behavior of Complex CoC₆₀(OH)

1.
Department of Chemistry, Xiamen University, Xiamen 361005

Corresponding author: WU Zhen-Yi,
Received Date: 10 March 2003
Available Online: 18 October 2003
Fund Project: 福建省自然科学基金(E0110002) (E0110002)高等学校博士学科点专项科研基金(98038410) (98038410)

The fullerene compound CoC₆₀(OH) has been prepared by the reaction of C₆₀^- anion with Co(Ⅱ) hydrous salt under nitrogen atmosphere and refluxing, and the title compound is characterized by FAB-MS, elemental analysis, FT-IR, XPS, UV-Vis and ¹H NMR. The results prove the presence of C-Co and -OH groups in the resultant, and coovalent of Co bonding to C 60. The apparent charge distribution of the resultant appeaers to be CO²⁺C₆₀^-(OH)^-, and there are three kinds of carbons with different electron density. The result of redox experiment indicates that the reduction potential of the compound is more negative than that of pure C₆₀.
- fullerene-cobalt compound,
- synthesis,
- redox behavior
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Synthesis and Redox Behavior of Complex CoC₆₀(OH)