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Citation: WANG Jing-Ping, WANG Zi-Liang, NIU Jing-Yang. Hydrothermal Synthesis and Structure of a Super Molecular Compound [C₆H₁₁NH₃]₆[P₂Mo₁₈O₆₂]·4H₂O[J]. Chinese Journal of Applied Chemistry, ;2004, 21(1): 45-48. shu

Hydrothermal Synthesis and Structure of a Super Molecular Compound [C₆H₁₁NH₃]₆[P₂Mo₁₈O₆₂]·4H₂O

1.
School of Chemistry and Chemical Engineering, Henan University, Kaifeng 475001

Corresponding author: NIU Jing-Yang,
Received Date: 25 April 2003
Available Online: 14 July 2003
Fund Project: 河南省教育厅基金资助项目(20011500024) (20011500024)

A super molecular complex[C₆H₁₁NH₃]₆[P₂Mo₁₈O₆₂]·4H₂O was synthesized by hydrothermal method and characterized by X-ray single crystal diffractometer. The compound belongs to monoclinic, with space group P2₁. Cell units:a=1.330 4(3) nm, b=2.791 0(6) nm, c=1.337 7(3) nm, β=118.72(3)°,Z=2, V=4.355 9 nm³, R=0.044 3, R_w=0.058 6. It consists of a Wells-Dawson-type heteropolyanion P₂Mo₁₈O₆₂^6-, six protonized cyclohexylamine and four crystallization water molecules. Thermal analysis indicated it discomposes at 564 2℃.
- super molecular compound,
- hydrothermal method,
- Wells-Dawson structure,
- heteropoly com-pound
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Hydrothermal Synthesis and Structure of a Super Molecular Compound [C₆H₁₁NH₃]₆[P₂Mo₁₈O₆₂]·4H₂O