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Citation: LI Chao, CAO Chuan-Bao, ZHU He-Sun, LÜ Qiang, HUANG Fu-Lin. Preparation of Carbon Nitride Thin Films with High Nitrogen Content by Cathodic Electrodeposition[J]. Chinese Journal of Applied Chemistry, ;2004, 21(1): 36-40. shu

Preparation of Carbon Nitride Thin Films with High Nitrogen Content by Cathodic Electrodeposition

LI Chao ^a,b ,
CAO Chuan-Bao ^a,, ,
ZHU He-Sun ^a ,
LÜ Qiang ^a ,
HUANG Fu-Lin ^a

1.
a Research Center of Materials Science, Beijing Institute of Technology, Beijing 100081;
2.
b Department of Chemical Engineering, Zhengzhou Institute of Light Industry, Zhengzhou

Corresponding author: CAO Chuan-Bao,
Received Date: 12 March 2003
Available Online: 14 July 2003
Fund Project: 国家自然科学基金(20171007) (20171007)博士点基金(1999000718)资助项目 (1999000718)

Carbon nitride films with high nitrogen content were obtained by cathodic electrodeposition onto glass substrates coated with indium tin oxide(ITO-coated glass) in solutions of dicyandiamide in acetonitrile. The XPS results showed that the maximum value of the N/C atomic ratio in the films was 1.22, close to the stoichiometric value of C₃N₄, and carbon-nitrogen bond forms were mainly C-N and C=N, as confirmed by FTIR spectroscopy. In Raman spectrum there are two peaks at 1 098 cm^-1 and 1 950 cm^-1 corresponding to C-N and C=N, which is seldom reported in literatures. The hardness and the Young's modulus of the sample obtained at 50℃、1 250 V were 11.31 GPa and 86 GPa, respectively. A polarization-competition reaction mechanism is proposed to interpret the results obtained.
- carbon nitride film,
- electrodeposition,
- hardness,
- Young's modulus
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