Citation:
ZHAO Yan, ZHANG Bing-Ru, LI Xia, LI Feng-Ting. Poly(aluminum chloride) and Its Coagulation Effect[J]. Chinese Journal of Applied Chemistry,
;2004, 21(2): 212-214.
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Poly(aluminum chloride)(PAC) solutions of different basicity were prepared from pure aluminum foil and hydrochloric acid. Aluminum species were investigated by 27Al NMR spectroscopy and the tridecameric polycation Al13 was detected. With the increase of PAC's basicity, the molar ratio of Al13 to Alm in PAC increases. The jar tests with kaolin water and water from Huangpu River at the same PACs dosage showed that the more basicity and content of Al13, the more effective the coagulation effect on water with middle-high turbidity, while only less effect of the basicity was observed on water with low turbidity.
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Keywords:
- poly aluminum chloride,
- basicity,
- Al13,
- 27Al NMR,
- coagulation
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