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Citation: BI Liang-Wu, LIU Xian-Zhang, XU Peng-Xiang, ZHAO Zheng-Dong, CHU Fu-Xiang. Direct Electrolytic Oxidation of p-tert-Butyl toluene[J]. Chinese Journal of Applied Chemistry, ;2004, 21(2): 209-211. shu

Direct Electrolytic Oxidation of p-tert-Butyl toluene

1.
a Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry, Nanjing 210042;
2.
b Department of Chemstry, Xiamen University, Xiamen

Corresponding author: BI Liang-Wu,
Received Date: 3 March 2003
Available Online: 15 October 2003
Fund Project:

The direct electrolytic oxidation of p-tert-butyl toluene in a mixture of sodium fluoborate, acetic acid and methanol using carbon rod as electrode has been studied. The main electrolytic oxidation products, p-tert-butylbenzaldehyde,p-tert-butylbenzyl methyl ether, p-tert-butyl benzaldehyde dimethyl acetal, and methyl p-tert-butylbenzoate were separated and identified by GC/MS. The relation between the oxidation pro-duct and the oxidation time in electrolytic oxidation was examined. The total yield of p-tert-butylbenzaldehyde and p-tert-butyl benzaldehyde dimethyl acetal was over 88% in period of 30 h oxidation.
- p-tert-butyl toluene,
- direct electrolytic oxidation,
- methoxylation
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