Citation:
WANG Jun, LI Jie, LI Cui-Qin, WANG Tian-Feng, YANG Jin-Zong. Surface Property of Dendrimer PAMAM Aqueous Solution[J]. Chinese Journal of Applied Chemistry,
;2004, 21(2): 206-208.
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Three polyamidoamine(PAMAM) dendrimers have been synthesized by divergence method with ethylenediamine as core. The surface tensions of aqueous solution of different generation PAMAM were determined by traditional surfactant method. The results showed that the whole PAMAM doesn't have surface acti-vity and the half PAMAM have certain surface activity. Their critical micelle concentrations(CMC) were obtained from surface tension curves, and the hydrophile-lipophile balance number(HLB), saturated adsorption capacity, molecular cross section area and molecular diameter were calculated. The results revealed that the molecular diameter of 0.5G, 1.5G and 2.5G PAMAM were 0.743, 0.998 and 1.371 nanometer, respe-ctively. The dendrimer obtained was also proved to be of nanometer order.
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Keywords:
- polyamidoamine,
- surface tension,
- CMC,
- HLB value,
- saturation adsorption capacity
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