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Citation: ZHANG Chen, ZHANG Li, LI Guo-Ming. Synthesis of Poly(siloxane-acrylate) Microemulsion and Its Property[J]. Chinese Journal of Applied Chemistry, ;2004, 21(2): 182-186. shu

Synthesis of Poly(siloxane-acrylate) Microemulsion and Its Property

1.
Department of Chemistry, South China Normal University, Guangzhou 510631

Corresponding author: ZHANG Li,
Received Date: 15 May 2003
Available Online: 15 August 2003
Fund Project: 广东省科委重点攻关项目(2KM06202S) (2KM06202S)广州市高新技术(2000Z08601)资助项目 (2000Z08601)

The poly(siloxane-acrylate) microemulsions were synthesized using K₂S₂O₈ as initiator and copolymer nanoparticles were obtained. The effects of polymerization methods, the TS/SDS mass ratio and the content of siloxane on the polymerization and properties of the microemulsion were investigated. The best results were obtained by seeding semi-continuous emulsion polymerization, by which the poly(siloxane-acrylate) microemulsion with average particle size of 46.1 nm could be obtained with low surfactant concentration(2.5%) and relatively high copolymer content(30%).
- siloxane,
- acrylates,
- copolymer microemulsion,
- synthesis
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