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Citation: LI Jian-Zhang, YANG Hua, QIN Sheng-Ying. Synthesis of N-[4-(2-Hydroxy ethoxyl)benzoyl]-N-phenyl hydroxylamine and Biomimetic Catalytic Performance in Epoxidation of Styrene over Its Manganese(Ⅲ)Complex[J]. Chinese Journal of Applied Chemistry, ;2004, 21(2): 109-112. shu

Synthesis of N-[4-(2-Hydroxy ethoxyl)benzoyl]-N-phenyl hydroxylamine and Biomimetic Catalytic Performance in Epoxidation of Styrene over Its Manganese(Ⅲ)Complex

1.
Faculty of Chemistry, Sichuan University, Chengdu 610064

Corresponding author: QIN Sheng-Ying,
Received Date: 15 May 2003
Available Online: 15 September 2003
Fund Project: 国家自然科学基金资助项目(20072025) (20072025)

The title compound and its manganese(Ⅲ)complex MnL₂¹Cl were prepared for catalytic epoxidation of styrene under the ambient temperature and pressure. The effects of reaction temperature, concentration of styrene, axial ligand, iodosobenzene and catalyst amount as well as the terminal group of the substituent bonded to the ligand on the biomimetic catalytic performance of the manganese(Ⅲ) complex were investigated. The result indicates that the catalytic activity(conv. of styrene 39.6%) of MnL₂¹Cl, which contains hydroxyl group (OH) as the terminal group of the substituent bonded to the ligand is higher than that of containing acetoxyl group (CH₃COO) as the terminal group, while the selectivity of epoxidation of (93.9%) is lower than that of MnL₂²Cl (100%) under the same optimization condition.
- hydroxamic acid,
- manganese(Ⅲ)complex,
- biomimetic catalysis,
- styrene epoxidation
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