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Citation: WANG Wen, LIN Mei-Juan, ZHANG Wen-Gong. Preparation of Praseodymium triisooctanyl oxide/PS Hybrid Materials by Non-water Gel in situ Polymerization[J]. Chinese Journal of Applied Chemistry, ;2004, 21(3): 286-290. shu

Preparation of Praseodymium triisooctanyl oxide/PS Hybrid Materials by Non-water Gel in situ Polymerization

1.
College of Chemistry and Materials, Fujian Normal University, Fuzhou 350007

Corresponding author: WANG Wen,
Received Date: 22 May 2003
Available Online: 20 November 2003
Fund Project: 福建省自然科学基金资助项目(E0120002) (E0120002)

The polystyrene(PS) hybrid materials were obtained by the in situ polymerization from a gel by mixing of styrene and praseodymium triisooctanyl oxide Pr(i-C₈) in the absence of water. The materials have been characterized by FT-TR, TG-DTA, DMTA, ESEM, UV and fluorescence spectrometry. The process avoids the aggregation of rare earth in the materials. The introduction of praseodymium triisooctanyl oxide improves the heat resistance and fluorescence intensity of the hybrid. The materials with 4.0%(mass fraction) praseodymium have better transparency. ESEM reveals the crosslinked network structure of PS hybrid material.
- praseodymium triisooctanyl oxide,
- polystyrene,
- hybrid materials
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