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Citation: WU Zhen-Yi, LI Bin, YANG Sen-Gen, LIN Yong-Sheng, CHENG Da-Dian, ZHAN Meng-Xiong. Synthesis and Characterization of Complex C₆₀Ru(OCOCF₃)(CO)(PPh₃)[J]. Chinese Journal of Applied Chemistry, ;2004, 21(4): 361-364. shu

Synthesis and Characterization of Complex C₆₀Ru(OCOCF₃)(CO)(PPh₃)

1.
Department of Chemistry, Xiamen University, Xiamen 361005

Corresponding author: ZHAN Meng-Xiong,
Received Date: 28 June 2003
Available Online: 31 December 2003
Fund Project: 福建省自然科学基金(E0110002、F0210010) (E0110002、F0210010)高等学校博士学科点专项科研基金(98038410) (98038410)

Fullerene complex C₆₀Ru(OCOCF₃)(CO)(PPh₃) was perpared by reduction-substitution reactionof C₆₀ with Ru(OCOCF₃)₂(CO)(PPh₃)₂ under nitrogen atmosphere and refluxing, and the complex was characterized by elemental analysis, FT-IR, UV-vis,¹³CNMR and XPS. The results showed that in complex each moiety of PPh₃, ^-OCOCF₃, and CO takes one coordination site from the central metal, and C₆₀ takes the two remaining sites in σ-π back-bonding. The redox experiments of the complex indicated the reduction potential of the complex was more negative than that of the pure C₆₀.
- fullerene,
- ruthenium complex,
- cyclic voltammetry,
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Synthesis and Characterization of Complex C₆₀Ru(OCOCF₃)(CO)(PPh₃)