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Citation: WU Zhi-Chuan, TAO Ting-Xian, WANG Xue-Qian, CAO Xu, BI Song-Mei, FENG Hao. Synthesis of Polyvinyl Acetate Complexes with Fe(Ⅲ) Co(Ⅱ) and Ni(Ⅱ)[J]. Chinese Journal of Applied Chemistry, ;2004, 21(4): 352-356. shu

Synthesis of Polyvinyl Acetate Complexes with Fe(Ⅲ) Co(Ⅱ) and Ni(Ⅱ)

1.
Anhui University of Tecnology and Science, Wuhu 241000

Corresponding author: WU Zhi-Chuan,
Received Date: 25 August 2003
Available Online: 18 December 2003
Fund Project: 国家自然科学基金(20271001) (20271001)安徽省自然科学基金(00047419) (00047419)

Three polyvinyl acetate(PVAc) complexes with Fe(Ⅲ), Co(Ⅱ) and Ni(Ⅱ) have been synthesized by the reaction of polyvinyl acetate, respectively, with CoCl₂, NiCl₂ and FeCl₃ in THF at room tempre-ture and one hour was appropriate for reaction. The mole ratio of metal ion to[-CH₂-CH(OCOCH₃)-] segment as found by conductivity measurement was 1:4 in complexes PVAc-Co(Ⅱ) and PVAc-Ni(Ⅱ), but it was 1:3 to 1:6 and more in complex PVAc-Fe(Ⅲ). IR spectra and XPS showed the complex PVAc-Fe(Ⅲ) is formed by non-paired electrons from oxygen atom of CH₃COO group in PVAc with metal ions. TG-DTA revealed the heat stability of complexes was higher than that of PVAc. The proposed structures of the complexes were given.
- polyvinyl acetate,
- metal complex,
- Fe,
- Co,
- Ni,
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