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Citation: DUAN Ming, HU Xing-Qi, ZUO Xiao-Ling, CHEN Yuan-Dong. Synthesis of a Cationic Gemini Surfactant with Amide Group[J]. Chinese Journal of Applied Chemistry, ;2004, 21(5): 538-540. shu

Synthesis of a Cationic Gemini Surfactant with Amide Group

1.
Department of Chemical Engineering, Southwest Petroleum Institute, Chengdu 610500

Corresponding author: HU Xing-Qi,
Received Date: 18 July 2003
Available Online: 20 November 2003
Fund Project: 油气藏地质及开发工程国家重点实验室开放基金(PLN0120) (PLN0120)

A novel Gemini surfactant bis[N,N'-(dodecanoylamino)ethyl]triethylenediamine bromide(BDEDE) was synthesized from ethyl bromide and bis(2-dodecanoylaminoethyl) ethylene diamine(BDEE), the latter was prepared from lauric acid and N,N'-bis(2-aminoethyl) ethylenediamine. The structure of the Gemini surfactant was characterized by elemental analysis, IR, ¹H NMR and ¹³C NMR. Its critical micelle concentration(0.105 mmol/L) and γ_cmc(31.0 mN/m) were determined. The cmc value of Gemini surfactant decreased by appoximately two orders of magnitude than cmc of dodecyltrimethylammonium bromide.
- Gemini surfactant,
- synthesis,
- surface activity
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