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Citation: LIU Lei-Li, LI Feng-Sheng, TAN Ling-Hua, LI Min, YANG Yi. Effect of Nanometer Metal Powders on the Thermal Decomposition of Ammonium Perchlorate[J]. Chinese Journal of Applied Chemistry, ;2004, 21(5): 488-492. shu

Effect of Nanometer Metal Powders on the Thermal Decomposition of Ammonium Perchlorate

1.
National Special Superfine Powder Engineering Research Center, Nanjing University of Science & Technology, Nanjing 210094

Corresponding author: LIU Lei-Li,
Received Date: 4 July 2003
Available Online: 2 November 2003

The decomposition of ammonium perchlorate(AP) in the presence of nanometer metal powders has been investigated by DTA. The results show that nanometer Cu, Ni and Al powders clearly decreased the high decomposition temperature of AP by 130.2, 112.9 and 51.8℃ respectively, as compared with that of AP without metal powder, showing good catalytic effects on the higher temperature decomposition of AP. Nanometer Cu powder also obviously decrases the low decomposition temperature of AP by 35.1℃, whereas the nanometer Ni and Al powders increased it. The catalytic effects of micron metal powders on the high temperature decomposition of AP are less than that of nanometer metal powders, but all the micron metal powders decrease the low decomposition temperature of AP.
- nanometer metal powder,
- ammonium perchlorate,
- catalysis,
- thermal decomposition
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