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Citation: MA Xue-Bing, FU Xiang-Kai, WANG Ning. Synthesis of Water-soluble Sulphonated phosphines[J]. Chinese Journal of Applied Chemistry, ;2004, 21(5): 464-468. shu

Synthesis of Water-soluble Sulphonated phosphines

1.
College of Chemistry and Chemical Engineering, Southwest Normal University, Chongqing 400715

Corresponding author: FU Xiang-Kai,
Received Date: 27 June 2003
Available Online: 12 December 2003
Fund Project: 重庆市科委应用基础资助项目(20006262) (20006262)

Two sulphonated phosphine ligands [(Et₃NH)₂][Ph₂PCH₂N(CH₂CH₂SO₃)₂(2a)and [(Et₃NH)₂] [O₃SCH₂CH₂N(CH₂PPh₂)CH₂CH₂N(CH₂PPh₂)CH₂CH₂SO₃](2b) with greater water solubi-lity were synthesized by reaction of amines containing sulfo-group with [Ph₂P(CH₂OH)₂]⁺Cl^- and characterized by NMR, MS and IR. The solubility of ligand 2a was 0.21 g/mL(in water) and 0.29g/mL(in ethanol) at 25℃. For compound 2b, where the molar ratio of SO₃H to Ph₂P was more low, the solubility was 0.11 g/mL(in water) and 0.15 g/mL(in ethanol), respectively.
- sulphonated phosphine,
- water soluble,
- synthesis,
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