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Citation: CAO Hong, LU Sheng-Mei, HU Li-Min, LIU Zhao-Jie. Synthesis and Biological Activity of Pyrethroids Containing Phosphonyl Moiety[J]. Chinese Journal of Applied Chemistry, ;2004, 21(5): 442-445. shu

Synthesis and Biological Activity of Pyrethroids Containing Phosphonyl Moiety

1.
College of Chemistry, Central China Normal University, Wuhan 430079

Corresponding author: LIU Zhao-Jie,
Received Date: 11 July 2003
Available Online: 20 September 2003
Fund Project: 国家重点科技攻关计划(975630205)资助项目 (975630205)

Four 2-(4-chlorophenyl)-3-methyl-butyl phosphorates and four 3-(2,2-dichloroviny)-2,2-dimethyl-cyclopropane carboxyl phosphorates were synthesized from the intermediate α-hydroxylaryl phosphorates with 2-(4-chlorophenyl)-3-methyl-butyl chloride and 3-(2,2-dichlorovinyl)-2,2-dimethyl-cyclopropane carbonyl chloride, respectively. All compounds synthesized were identified by ¹H NMR, IR and MS. Preliminary bioassay showed that compounds 4b, 4d and 5a, have consierable acaridcidal activities.
- pyrethroid,
- α-hydroxyl phosphorate,
- synthesis,
- insecticide
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