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Citation: YANG Wei-Jun, GUO Can-Cheng. Metalloporphyrins and Their Biomimetic Catalytic Oxidation for Alkanes[J]. Chinese Journal of Applied Chemistry, ;2004, 21(6): 541-545. shu

Metalloporphyrins and Their Biomimetic Catalytic Oxidation for Alkanes

YANG Wei-Jun ,
GUO Can-Cheng ^,

1.
College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082

Corresponding author: GUO Can-Cheng,
Received Date: 20 August 2003
Available Online: 31 December 2003
Fund Project: 国家自然科学基金(20376018) (20376018)国家"八六三"计划(2002AA321070)资助课题 (2002AA321070)

The structure, kinds and applications of metalloporphyrins are introduced in this paper. The recent researches on the biomimetic oxidation of alkanes catalyzed by metalloporphyrins are reviewed with the emphasis on the oxidation of cyclohexane to cyclohexanone by air. It is the first case of the industrial biomimetic oxidation for hydrocarbon with air using metalloporphyrins as catalyst.
- metalloporphyrin,
- biomimetic catalysis,
- oxidation,
- alkane,
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