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Citation: HUANG Jie, XIE Chuan, PAN Gu-Ping, WANG Qian. Synthesis and Photoinitiation Property of 1-(4-Aminophenyl)-2-(1-piperidino)-1-propanone hydrochloride[J]. Chinese Journal of Applied Chemistry, ;2004, 21(7): 745-747. shu

Synthesis and Photoinitiation Property of 1-(4-Aminophenyl)-2-(1-piperidino)-1-propanone hydrochloride

1.
College of Chemical Engineering, Sichuan University, Chengdu 610065

Corresponding author: XIE Chuan,
Received Date: 25 August 2003
Available Online: 31 December 2003
Fund Project:

1-(4-aminophenyl)-2-(1-piperidino)-1-propanone hydrochloride,a sort of water-soluble photoinitiator,was synthesized from acetanilide in three steps,i.e.Friedel-Crafts acylation,α-bromination,amination and hydrochlorination,and its structure was analyzed by IR,MS,UV,elemental analysis,¹H NMR.During the 3rd step,water acted as solvent and piperidine was dripped in at ambient temperature.After reaction at 40℃ for 2 h,the mixture was treated with 15%(volume fraction) HCl.The yield was 60.7%.The product has good solubility and photoinitiability.In the air with the distance of 20 cm,the curing time of photosensitive prepolymer was 10s only.
- aminoacetophenone,
- water-soluble,
- photoinitiator
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