Citation:
DUAN Ming, HU Xing-Qi, . Synthesis of Cationic Hydrophobically Modified Acrylamide Copolymers[J]. Chinese Journal of Applied Chemistry,
;2004, 21(8): 806-809.
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A surface-active macromonomer(VBDMOAC) was synthesized from p-vinyl benzyl chloride and octadecyl dimethyl amine. Its structure was identified by measurement of chlorine content, IR and 1H NMR. Its cmc and γcmc were determined to be 1.19×10-4 mol/L and 41.4 mN/m, respectively. Compared to AM-AA copolymer prepared in the same conditions, the intrinsic viscosities of the copolymers obtained from ternary polymerization of VBDMOAC, AM and AA in aqueous solvent showed that VBDMOAC have a higher polymerization activity. The terpolymer (VBDMOAC-AM-AA) was verified by its UV band at 224 nm and IR band at 1454 cm-1.
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