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Citation: NIU Yong-Sheng, QIU Ming-Yan, LI Jian-Ping. Synthesis of Arylacyl-aryl diazene Compounds[J]. Chinese Journal of Applied Chemistry, ;2005, 22(1): 108-110. shu

Synthesis of Arylacyl-aryl diazene Compounds

1.
a School of Materials Science and Engineering, Wuhan University of Science and Technology, Wuhan;
2.
b Department of Chemical Engineering, Anyang University, Anyang;
3.
c College of Chemistry and Environmental Science, Henan Normal University, Xinxiang 453002

Corresponding author: LI Jian-Ping,
Received Date: 21 February 2004
Available Online: 11 June 2004

Ten arylacyl-aryl diazene compounds were synthesized in yields of 89.6%~95.6% under mild conditions with 4-hydroxy-2,2,6,6-tetramethyl-1-piperidinyloxyl as phase-transfer catalyst in dehydrogenation of arylacyl-arylhydrazines. Their structures were confirmed by elemental analysis, IR and ¹H NMR spectra. The reaction mechanism was discussed.
- arylacyl-aryl azo compound,
- piperidinyloxyl nitride free radical,
- arylacyl-arylhydrazine,
- phase transfer catalysis
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