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Citation: MA Wen, CHEN He-Ping, SUN Mei, ZHANG Sheng-Yi, WU Jie-Ying, TIAN Yu-Peng, JIANG Min-Hua. Synthesis, Crystal Structure and Optical Limiting Properties of a Novel Fluorenone Derivative[J]. Chinese Journal of Applied Chemistry, ;2005, 22(1): 67-70. shu

Synthesis, Crystal Structure and Optical Limiting Properties of a Novel Fluorenone Derivative

MA Wen ^a ,
CHEN He-Ping ^b ,
SUN Mei ^a ,
ZHANG Sheng-Yi ^a ,
WU Jie-Ying ^a ,
TIAN Yu-Peng ^a,c,d,, ,
JIANG Min-Hua ^c

1.
a Department of Chemistry, Anhui University, Hefei 230039;
2.
b Department of Physics, Anhui University, Hefei 230039;
3.
c State Key Laboratory of Crystal Material, Shandong University, Jinan;
4.
d State Key Laboratory of Coordination Chemistry, Nanjing

Corresponding author: TIAN Yu-Peng,
Received Date: 22 February 2004
Available Online: 16 June 2004
Fund Project: 国家自然科学基金资助项目(50272001,50335050) (50272001,50335050)安徽省自然科学基金项目(03044701) (03044701)安徽省人才开发基金(2002Z021)资助 (2002Z021)

A novel fluorenone derivative, fluorenone-4-(methoxy) benzaldehyde dihydrazon, which has optical limiting capability, was synthesized and characterized by IR, electronic spectra, elemental analysis, and single crystal X-ray diffraction analysis. The crystal determination results show the molecule has well planarity with high delocalization of π electrons in the system. Optical limiting capability of this compound was measured by means of the Z-scan technique. The result shows that this compound has good optical limiting to 532 nm wavelength light of Nd:YAG pumping laser. The two photon absorption cross-section σ is 3.96×10^-46 cm⁴s/photon.
- fluorenone derivative,
- crystal structure,
- optical limiting properties
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