Citation:
HU Long-Fei, YANG Bo-Lun, LI Fu-Hua, WU Ying-Ying. Separation of tert-Butyl alcohol-Water Mixtures on Modified Chitosan Composite Membrane[J]. Chinese Journal of Applied Chemistry,
;2005, 22(1): 5-8.
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By blending chitosan(CTS) with polyvinyl alcohol(PVA) and crosslinking them with glutaraldehyde, a modified chitosan pervaporation membrane with better selectivity and higher permeation flux was prepared. The effects of methodology of membrane formation, pervaporation temperature and the composition of feed solution on the separation performance for tert-butyl alcohol(TBA)-water mixtures were examined in com parison with the polyvinyl alcohol/polyacrylonitrile composite membranes. Experimental results show that the modified chitosan composite membrane displayed the best separation factor of 3 500 and the total flux was 132 g/(m2·h) when the pervaporation temperature was 343 K and the amount of TBA in feed solution was in the range of 80% to 92%.
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Keywords:
- chitosan,
- pervaporation,
- membrane separation,
- tert-butyl alcohol
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