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Citation: SUN Zhan-Hui, WANG Yu, SUN Jin-Hua. Evaluation of Autoignition of Organic Peroxides with Small Sample Mass[J]. Chinese Journal of Applied Chemistry, ;2005, 22(1): 1-4. shu

Evaluation of Autoignition of Organic Peroxides with Small Sample Mass

1.
State Key Laboratory of Fire Science, University of Science and Technology of China, Hefei 230027

Corresponding author: SUN Zhan-Hui,
Received Date: 29 December 2003
Available Online: 9 August 2004
Fund Project: 九七三项目(2001CB409600) (2001CB409600)

A method for the evaluation of the autoignition hazard from organic peroxides is proposed based on the calculation of the self-accelerating decomposition temperature(SADT) via the experiment by means of a C80Ⅱ microcalorimeter. The chemical kinetic parameters of some organic peroxides were calculated using heat flux data measured by virtue of the C80 microcalorimeter, and their SADTs were obtained based on the Semenov model. The SADTs estimated from the C80 data are in good agreement with the US-TEST results.
- organic peroxide,
- thermal autoignition hazard,
- self-accelerating decomposition temperature,
- micro calorimeter
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