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Citation: SHEN Yu-Hua, HAN Cheng-Xiang, XIE An-Jian, XIA Bing, YANG Jia-Xiang. Preparation of Mixed 3-Ferrocenyl-2-butylene acid/Octadecylamine Monolayer[J]. Chinese Journal of Applied Chemistry, ;2005, 22(2): 204-206. shu

Preparation of Mixed 3-Ferrocenyl-2-butylene acid/Octadecylamine Monolayer

1.
a School of Chemistry and Chemical Engineering, Anhui University, Hefei 230039;
2.
b State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing

Corresponding author: SHEN Yu-Hua,
Received Date: 18 March 2004
Available Online: 13 September 2004
Fund Project: 国家自然科学基金资助项目(20031010,20371001,20471001) (20031010,20371001,20471001)

An amphiphilic ferrocene derivative 3-ferrocenyl-2-butylene acid(FCA) was synthesized. The mixed FCA/octadecylamine(ODA) monolayers on aqueous subphase were studied by means of surface pressure-molecule area(π-A) isotherm, dπ/dA-A curve and the plot of the apparent area of ODA vs x(ODA). The results indicate that the FCA itself did not form monolayer, but the mixed FCA/ODA mono-layers were stable when the mole fraction of ODA was more than 25%, the mixed monolayers possessed the best stability and the highest incompressibility when the mole ratio of FCA to ODA is 1 to 1.
- ferrocene derivative,
- octadecylamine,
- mixed monolayer,
- preparation
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