Citation:
WANG Guang-Feng, LI Mao-Guo, KAN Xian-Wen, GAO Ying-Chun, FANG Bin. Prepartion of Ag Nanoparticle/L-cysteine Modified Gold Electrode and Its Application[J]. Chinese Journal of Applied Chemistry,
;2005, 22(2): 168-171.
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A silver nanoparticle/L-cysteine modified gold electrode was prepared and its electrochemical behaviour was evaluated by means of electrochemical impedance spectrocscopy(EIS) and cyclic voltammetry(CV). The surface coverage of Ag on the modified electrode((5.7±0.4)×10-10 mol/cm2) was calculated based on the linear relationship between peak current and scan rate. The modified electrode accelerates the response of redox of hydroquinone stably. The oxidation peak current is linearly changed with the concentration of hydroquinone at the modified electrode in the concentration range of 3.0×10-3 to 2.0 mmol/L. The linear regression equation is ip(μA)=-0.056+1.137c(μmol/L), with correlation coefficient λ=0.998 1, detection limit=0.172 μmol/L, signal-to-noise ratio=3.
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