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Citation: HU Wei-Bing, LIU Hong-Xia, YU Ai-Nong, CHEN Xiong-Bo. Syntheses and Characterization of Seven Derivatives of 1,3-Dithiocyclohexane[J]. Chinese Journal of Applied Chemistry, ;2005, 22(3): 340-342. shu

Syntheses and Characterization of Seven Derivatives of 1,3-Dithiocyclohexane

1.
a School of Chemistry and Environmental Engineering, Hubei Institude for Nation alities, Enshi 445000;
2.
b Collge of Chemistry, Central China Normal University, Wuhan

Corresponding author: HU Wei-Bing,
Received Date: 16 June 2004
Available Online: 23 October 2004
Fund Project: 国家民委重点科研项目(200145) (200145)湖北省教育厅重点项目(2003A007) (2003A007)

Seven derivatives of 1,3-dithiocyclohexane were prepared via the reaction of 7 aldehydes (or ketones) with Bunte's salt prepared from 1,3-dichloropropane and sodium thiosulfate.The procedure has the feature of easier operation,shorter reaction time and higher yield.The yields of seven derivatives of 1,3-dithiocyclohexane are between 58% and 75%.The optimum molar ratio of 1,3-dichloropropane to sodium thiosulfate was 1:1 in the preparati on of Bunte's salt.The structures of seven derivatives were characterized by means of IR,¹H NMR,MS.
- Bunte's salt method,
- synthesis,
- dithiocyclohexane,
- perfume,
- characterization
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