Citation:
PENG Qi, XU Qun, WANG Yu-Dong, LIU Min-Ying, ZHAO Qing-Xiang. Preparation of Poly(Acrylic Acid)/Nylon1313 and Polystyrene/Nylon1313 Blends Through Polymerization in Supercritical CO2-Swelling Nylon1313[J]. Chinese Journal of Applied Chemistry,
;2005, 22(3): 337-339.
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Poly (acrylic acid)/nylon1313 and polystyrene/nylon1313 blends were prepared using supercritical CO2 as both the substrate-swelling agent and the monomer/initiator carrier.The desorption of CO2 from CO2-saturated nylon1313 is linearly dependent on the logarithm of time.Both IR and SEM data show the existence of the PAA or the PS phases within the nylon1313 matrix in the blends.Compared to nylon1313,the heat of fusion of CO2-plasticized nylon1313 is greater,and that of the CO2-plasticized PAA/nylon1313 and PS/nylon1313 blends are smaller.
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Keywords:
- supercritical CO2,
- poly (acrylic acid),
- polystyrene,
- nylon 1313,
- blend
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