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Citation: LIAN Hui-Qin, WU Xue, CUI Xiu-Guo. Synthesis and Photochromism of 5-(Quinolin-8-yloxy)-6,11-naphthacenediquinone[J]. Chinese Journal of Applied Chemistry, ;2005, 22(3): 308-311. shu

Synthesis and Photochromism of 5-(Quinolin-8-yloxy)-6,11-naphthacenediquinone

1.
Department of Chemical Engineering & Polymer Science, Yanbian University, Yanji 133002

Corresponding author: WU Xue,
Received Date: 25 June 2004
Available Online: 15 November 2004
Fund Project: 吉林省教育厅基金(2002-6)资助项目 (2002-6)

A novel photochromic compound,5-(quinolin-8-yloxy)-6,11-naphthacenediquinone (compound 2) was synthesized by reacting 5-chloro-6,11-naph thacenediquinone with 8-hydroxyquinoline in dry DMSO in the presence of potassium carbonate.Like phenoxynaphthacenequinone,the compound shows similar photo-chromic property in benzene,chloroform and DMSO.It exhibits a characteristic double-peak at about 450 nm and 480 nm with an isobestic point at about 400 nm under irradiation of UV light at 365 nm.It was also observed that the position of the longwave absorption bands for compound 2 only slightly depends on the nature of the solvent used.
- naphthacendiequinone,
- quinoline,
- photochromism,
- photoisomerization
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