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Citation: REN Hong-Xia, LU Xiao-Quan, WANG Yun-Pu. Synthesis and Catalytic Performance of Polymer-Bound Metalloporphyrin[J]. Chinese Journal of Applied Chemistry, ;2005, 22(3): 259-263. shu

Synthesis and Catalytic Performance of Polymer-Bound Metalloporphyrin

1.
Institute of Polymer, Northwest Normal University, Lanzhou 730070

Corresponding author: WANG Yun-Pu,
Received Date: 10 May 2004
Available Online: 30 October 2004
Fund Project: 国家自然科学基金(20275031)资助项目 (20275031)西北师范大学创新工程(KJCX01) (KJCX01)高等学校优秀青年教师科研奖励计划(TRAPOYT) (TRAPOYT)

Polymer-bound metalloporphyrins with polyglycol chains were synthesized and their catalytic performances on the oxidation of cyclohexene were investigated.The experimental results show that the synthesized manganese (Ⅱ) and cobalt (Ⅱ) porphyrins bound to chloromethylated polystyrene with polyglycol chains are efficient catalysts for the oxidation of cyclohexene.The conversion is 88% for the oxidation of cyclohexene catalyzed by manganese (Ⅱ) porphyrin bound to chloro-methylated polystyrene.The catalytic performances of synthesized manganese (Ⅱ) and cobalt (Ⅱ) porphyrins are better than those of simple metalloporphyrins;however,the catalytic performance of polymer-bound metalloporphyrins with phase transfer catalyst polyglycol chains are decreased.
- polymer-bound metalloporphyrin,
- cyclohexene,
- catalytic oxidation
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