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Citation: MA Lu-Fang, WANG Li-Ya, DU Zhong-Xiang, LIANG Fu-Pei, ZHANG Man-Bo, YU Kai-Bei. Syntheses, Crystal Structure and Antibacterial Activity of Rare Earth(Pr,Yb) 1-D chain Complexes with N-p-Tolylsulfonyl-β-Alanine[J]. Chinese Journal of Applied Chemistry, ;2005, 22(3): 246-249. shu

Syntheses, Crystal Structure and Antibacterial Activity of Rare Earth(Pr,Yb) 1-D chain Complexes with N-p-Tolylsulfonyl-β-Alanine

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a Department of Chemistry, Luoyang Teacher's College, Luoyang 471022;
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b Department of Chemistry, Guangxi Normal University, Guilin;
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c Chengdu Center of Analysis and Measurement, Chinese Academy of Sciences, Chengdu

Corresponding author: WANG Li-Ya,
Received Date: 28 June 2004
Available Online: 8 September 2004
Fund Project: 国家自然科学基金(20471026) (20471026)河南省自然科学基金(0311021200)资助项目 (0311021200)

Two rare earth complexes with formula [Ln₂(H₂O)₄(Ts-β-Ala^-)₆]_n·4nH₂O (where Ln=Pr (1),Yb (2),Ts-β-Ala^-=N-p-tolysulfonyl-β-Alanine anion) were prepared and their crystal structures were determined by X-ray diffract ometry.Both the complexes are monoclinic,with space group P2₁/n.The crystal data are:(1):a=0.953 2(3) nm,b=1.909 5(6) nm,c=2.298 0(8) nm,β=99.73(2)°,Z=4,D_c=1.514×10^-3 g/cm³;(2):a=0.956 9(1) nm,b=1.888 0(3) nm,c=2.286 8(3) nm,β=100.41(1)°,Z=4,D_c=1.589×10^-3 g/cm³.The two complexes in crystal have one-dimensional chain structures and are different in bridging type of carboxyl groups.The coordination number of the Pr^Ⅲ ion is nine and that of the Yb^Ⅲ ion is eight.The complexes have stronger antibacterial activity than the ligand does.
- N-p-tolysulfonyl-β-alanine,
- rare earth complex,
- crystal structure,
- antibacterial activity
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